JAMB UTME - Chemistry - 2018
Frage 1 Bericht
A quantity of electricity liberates 3.6g of Silver from its salt. What mass of aluminium Will be liberated from its salt by the same quantity of electricity? [Al = 27, Ag = 108].
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The amount of substance liberated at an electrode during electrolysis is directly proportional to the quantity of electricity passed through the solution. This is known as Faraday's laws of electrolysis. The key to solving this problem is to recognize that the same quantity of electricity is used to liberate both silver and aluminum from their respective salts. We can use the ratio of their molar masses to determine the mass of aluminum liberated. The molar mass of silver (Ag) is 108 g/mol, while the molar mass of aluminum (Al) is 27 g/mol. This means that it takes four times as many moles of aluminum to make the same mass as one mole of silver. Since the same quantity of electricity liberates 3.6g of silver from its salt, it will liberate four times as many moles of aluminum. Therefore, the mass of aluminum liberated is: (4 moles of Al) x (27 g/mol) = 108 g So, the mass of aluminum liberated is 0.108 g, or 0.1 g to one significant figure. Therefore, the answer is option D: 0.3g.
Frage 3 Bericht
A correct electrochemical series can be obtained from Na, Ca, Al, Mg, Zn, Fe, Pb, H, Cu, Hg, Ag, Au by interchanging
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Frage 4 Bericht
On which of the following is the solubility of a gaseous substance dependent?
I. Nature of solvent
II. Nature of solute
III. Temperature
IV. Pressure
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Frage 5 Bericht
Which of the following metals cannot replace hydrogen from water or steam?
Frage 6 Bericht
Which of the following is used to power steam engines?
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Coal is the fuel that is typically used to power steam engines. Coal is burned in a furnace to heat water and produce steam, which is then used to power a steam engine. The steam engine converts the energy from the steam into mechanical energy, which can be used to power machines or generate electricity. Coal is a fossil fuel that has been used for centuries as a source of energy, and it played a significant role in the industrial revolution, powering steam engines that were used to drive machines in factories and transport goods and people by train. Today, steam engines are less common as other forms of energy have taken their place, but they remain an important part of our history and technological development.
Frage 7 Bericht
Which of these sources of water may likely contain the least concentration of Ca2+ and Mg2+ ?
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The source of water that is likely to contain the least concentration of Ca2+ and Mg2+ is tap water. Tap water is treated and processed before it is made available for consumption, which often involves removing minerals such as calcium and magnesium. Spring water and river water, on the other hand, are naturally occurring and generally contain higher levels of minerals. Sea water has the highest concentration of minerals, including Ca2+ and Mg2+.
Frage 8 Bericht
The type of bonding in [Cu(NH3 )4 ]2+ is
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The type of bonding in [Cu(NH3)4]2+ is coordinate bonding. Coordinate bonding (also known as dative covalent bonding) is a type of covalent bonding where one atom (in this case, the nitrogen atom in NH3) donates a pair of electrons to another atom or ion (in this case, the copper ion Cu2+). The donating atom is called the ligand, and the receiving atom or ion is called the central metal ion. In [Cu(NH3)4]2+, each ammonia molecule (NH3) donates a lone pair of electrons on the nitrogen atom to the copper ion, forming four coordinate bonds between the ligands and the central copper ion. The presence of coordinate bonds is indicated by the use of square brackets around the coordination compound, and the charge on the compound is indicated by the superscript outside the brackets. Therefore, the answer is option A: coordinate.
Frage 9 Bericht
The general formula of alkanones is
Frage 11 Bericht
A balanced chemical equation obeys the law of
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A balanced chemical equation obeys the law of conservation of mass. This means that in a chemical reaction, the total mass of the reactants must be equal to the total mass of the products. In other words, atoms cannot be created or destroyed during a chemical reaction, only rearranged. For example, if we burn a piece of wood, the mass of the ashes and the gases released will be equal to the mass of the original wood. This is because the atoms in the wood (carbon, hydrogen, oxygen, etc.) are rearranged during the burning process to form new molecules, but the total number of atoms remains the same. By balancing a chemical equation, we ensure that the same number and type of atoms are present on both sides of the equation, which satisfies the law of conservation of mass.
Frage 12 Bericht
According to the Kinetic Theory an increase in temperature causes the kinetic energy of particles to
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The kinetic energy of particles increases with an increase in temperature. In the Kinetic Theory, temperature is related to the average kinetic energy of the particles in a substance. The higher the temperature, the faster the particles move, and the more energy they have. Think of it like this: if you throw a ball, it will have more energy and travel farther if you throw it harder. Similarly, if you heat up a substance, its particles will move faster and have more energy. So, the answer is that an increase in temperature causes the kinetic energy of particles to increase.
Frage 13 Bericht
The presence of ammonia gas in a desiccator can exclusively be removed by
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Frage 14 Bericht
(I). 3CuO(s) + 2NH3(g) -----> 3Cu(s) + 3H2O(l) + N2(g)
(II). 2NH3(g) + 3Cl2(g) -----> 6HCl(g) + N2(g)
(III). 4NH3(g) + 3O2(g) -----> 6H2O(l) + N2(g)
The reactions represented by the equations above demonstrate the
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Frage 15 Bericht
The salt that reacts with dilute hydrochloric acid to produce a pungent smelling gas which decolourizes acidified purple potassium tetraoxomanganate (VII) solution is
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Frage 16 Bericht
The boiling of fat and aqueous caustic soda is referred to as
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The boiling of fat and aqueous caustic soda is referred to as saponification. Saponification is the process of converting fat into soap through a reaction with an alkaline substance, such as caustic soda. The reaction results in the formation of soap (a salt of a fatty acid) and glycerol. This process is important in the manufacture of soap, as it allows the fat to be converted into a useful cleaning product.
Frage 17 Bericht
How many atoms are present in 6.0g of magnesium? [Mg = 24, N.A = 6.02 x 10 23 mol]
Frage 18 Bericht
A substance that is used as a ripening agent for fruits is
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The substance that is commonly used as a ripening agent for fruits is ethene. Ethene, also known as ethylene, is a natural plant hormone that is produced by fruits, especially during the ripening process. It is a colorless gas that can be easily synthesized and used as a ripening agent for fruits. When fruits are exposed to ethene, it triggers a series of biochemical reactions that accelerate the natural ripening process. This can help fruits to ripen faster and more uniformly, which is important for commercial purposes where fruits need to be sold quickly. The use of ethene as a ripening agent is regulated by food safety agencies, as excessive exposure to ethene can cause over-ripening and spoilage of fruits. However, when used in appropriate concentrations, ethene is a safe and effective way to promote the ripening of fruits.
Frage 19 Bericht
Which of the following separation techniques can be employed in obtaining solvent from its solution?
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The separation technique that can be employed in obtaining a solvent from its solution is evaporation. Evaporation is a process that involves heating a solution to vaporize the solvent, leaving behind the solute. The vaporized solvent can then be condensed and collected as a pure liquid. This technique is commonly used in industry and laboratory settings to recover solvents from solutions, as it is a simple and effective way to purify liquids. Distillation can also be used to separate a solvent from a solution, but it is a more complex process that involves boiling the solution and then condensing the vapors in a separate apparatus. Filtration and precipitation are not suitable for separating a solvent from a solution, as they are primarily used to separate solid particles from a liquid mixture.
Frage 20 Bericht
An element X forms the following compounds with chlorine; XCl4 , XCl3 , XCl2 . This illustrates the
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The element X forming different compounds with chlorine (XCl4, XCl3, and XCl2) illustrates the law of multiple proportions. This law states that when two elements combine to form more than one compound, the ratio of the masses of one element that combine with a fixed mass of the other element is always a whole number ratio. In this case, the ratio of chlorine to X in the different compounds (XCl4, XCl3, and XCl2) is 4:1, 3:1, and 2:1, respectively, which are all whole number ratios.
Frage 21 Bericht
The figure above shows the electrolysis of molten sodium chloride. Z is the
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The figure shows the electrolysis of molten sodium chloride. During electrolysis, an electric current is passed through a molten or dissolved ionic compound to separate the ions. The positive ions move towards the negative electrode (cathode) and the negative ions move towards the positive electrode (anode). In the figure, the electrode connected to the positive terminal of the battery is the anode and the electrode connected to the negative terminal is the cathode. At the anode, the negatively charged chloride ions (Cl-) lose electrons and are oxidized to form chlorine gas (Cl2). At the cathode, the positively charged sodium ions (Na+) gain electrons and are reduced to form liquid sodium metal (Na). Therefore, the answer is (a) anode where the Cl- ions are oxidized. Z is the anode in the figure.
Frage 22 Bericht
The Consecutive members of an alkane homologous series differ by
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The consecutive members of an alkane homologous series differ by a CH2 unit. This means that each successive member of the alkane series has one more CH2 unit than the previous member. For example, consider the simplest alkane, methane (CH4). The next member of the series is ethane (C2H6), which differs from methane by one CH2 unit. The next member after that is propane (C3H8), which differs from ethane by another CH2 unit. This pattern continues for all members of the alkane homologous series. The reason for this is that each carbon atom in the alkane chain must be bonded to four other atoms, which are usually hydrogen atoms. This means that each carbon atom in the chain can only bond to one other carbon atom. Therefore, the length of the alkane chain can only increase by adding CH2 units to the end of the chain. In summary, the consecutive members of an alkane homologous series differ by a CH2 unit because this is the only way to add length to the alkane chain while maintaining the required number of bonds for each carbon atom in the chain.
Frage 23 Bericht
What is the PH of 0.00 1 moldm3 solution of the sodium hydroxide
Frage 24 Bericht
What volume of oxygen will remain after reacting 8cm of hydrogen gas with 20cm of oxygen gas
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Frage 25 Bericht
A basic postulate of the kinetic theory of gases is that the molecules of a gas move in straight lines between collisions. This implies that
Frage 26 Bericht
The elements in the periodic table are listed in order of increasing
Frage 27 Bericht
The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as;
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The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as esterification. Esterification is the process of forming an ester, which is a type of organic compound, from an alcohol and an acid. The acid catalyst is used to speed up the reaction by providing a proton to the reaction mixture, which helps to form the ester. Esterification results in the loss of a water molecule from the reaction mixture, which makes the reaction a type of dehydration reaction. However, it is important to note that esterification is a specific type of dehydration reaction where the products are an ester and an alcohol. So, the answer is esterification.
Frage 28 Bericht
Elements P, Q, R, S have 6, 11, 15, 17 electrons respectively, therefore,
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Elements form bonds with other elements in order to attain a stable electron configuration, like the one found in noble gases. There are two types of bonds: covalent and ionic (also called electrovalent). In covalent bonds, two elements share electrons to attain a stable electron configuration. This type of bond is formed between two non-metal elements. In ionic bonds, one element donates electrons to another element, creating ions. This type of bond is formed between a metal and a non-metal element. Based on the information given, we can deduce the following: - P is a metal, as it has only 6 electrons. - Q is a non-Metal, as it has 11 electrons. - R is a metal, as it has 15 electrons. - S is a non-Metal, as it has 17 electrons. So, from this information, we can conclude that: - P will form an ionic bond with R, as P is a metal and R is a metal. - Q will form a covalent bond with S, as Q is a non-Metal and S is a non-Metal. Therefore, the correct answer is "Q will form a covalent bond with S."
Frage 29 Bericht
The constituent common to duralumin and alnico is
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The common constituent found in both duralumin and alnico is aluminum (Al). Duralumin is an alloy made up of aluminum, copper, manganese, and magnesium. It is known for its high strength and light weight, making it useful in various applications such as aerospace and construction. Alnico, on the other hand, is an alloy made of aluminum, nickel, cobalt, iron, and small amounts of other elements. It is used in the production of strong permanent magnets for various applications such as in motors, generators, and loudspeakers. So, even though duralumin and alnico have different properties and uses, they both contain the element aluminum.
Frage 30 Bericht
Calculate the pH of 0.05 moldm?3 H2 SO4
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To solve this problem, we need to use the formula for calculating the pH of a solution, which is: pH = -log[H+] where [H+] is the concentration of hydrogen ions in moles per liter. The given chemical equation is: H2SO4 + 2H2O → 2H3O+ + SO42- From this equation, we can see that one molecule of sulfuric acid (H2SO4) can donate two hydrogen ions (H+) to the solution, which means that the concentration of hydrogen ions is twice the concentration of sulfuric acid. Therefore, the concentration of hydrogen ions in this solution is: [H+] = 2 x 0.05 moldm^-3 = 0.1 moldm^-3 Now we can use the formula for pH: pH = -log[H+] pH = -log(0.1) pH = 1.00 Therefore, the pH of the solution is 1.00.
Frage 31 Bericht
Suitable reagents for the laboratory preparation nitrogen are
Frage 32 Bericht
The knowledge of half-life can be used to
Frage 33 Bericht
Diamond is a bad conductor of electricity because its bonding electrons are used in
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Diamond is a bad conductor of electricity because of its unique structure and bonding. The carbon atoms in diamond form a covalent network, where each carbon atom is bonded to four other carbon atoms. These bonds are strong and hold the atoms in a rigid three-dimensional structure called a crystal lattice. In a covalent bond, atoms share electrons to form a stable compound. In diamond, each carbon atom shares its valence electrons with four neighboring carbon atoms, forming a very strong covalent bond. All the valence electrons in the crystal lattice are used in covalent bond formation, which means there are no free or mobile electrons to carry an electric current. In other words, the electrons are tightly held in the covalent bonds, making it difficult for them to move around the crystal lattice and conduct electricity. In contrast, metals conduct electricity well because they have delocalized or free electrons that can move through the lattice of positively charged ions. So, diamond, being a covalent network solid, does not have free electrons that can carry an electric current, which is why it is a bad conductor of electricity.
Frage 34 Bericht
What mass of Cu would be produced by the cathodic reduction of Cu2+ when 1.60A of current passes through a solution of CuSO4 for 1 hour. (F=96500Cmol−1 , Cu=64)
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The reduction reaction that occurs at the cathode during the electrolysis of CuSO4" tabindex="0" class="mjx-chtml MathJax_CHTML" id="MathJax-Element-1-Frame">4, is: Cu2+" tabindex="0" class="mjx-chtml MathJax_CHTML" id="MathJax-Element-2-Frame">2+ + 2e- -> Cu(s) From this, we can see that each Cu2+ ion requires two electrons to be reduced to copper metal. Given the current (I = 1.60 A), time (t = 1 hour = 3600 s), and Faraday's constant (F = 96500 C/mol), we can calculate the total amount of charge that passes through the solution: Q = I*t = 1.60 A * 3600 s = 5760 C Using Faraday's law, we can relate the amount of charge that passes through the solution to the number of moles of electrons transferred during the reduction reaction: n = Q/F = 5760 C / 96500 C/mol = 0.0597 mol e- Since each Cu2+ ion requires 2 electrons to be reduced to copper metal, the number of moles of copper produced is half the number of moles of electrons transferred: mol Cu = 0.0597 mol e- / 2 = 0.0299 mol Cu Finally, we can convert the moles of copper produced to grams using the molar mass of copper: mass Cu = 0.0299 mol Cu * 64 g/mol = 1.91 g Therefore, the answer is 1.91 g of Cu produced. is correct.
Frage 35 Bericht
The choice of method for extracting a metal from its ores depends on the
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The choice of method for extracting a metal from its ores depends on the position of the metal in the electrochemical series. The electrochemical series is a list of metals arranged in order of their ability to gain or lose electrons. The metals at the top of the series (such as sodium and potassium) are very reactive and will readily lose electrons, while those at the bottom (such as gold and platinum) are less reactive and less likely to lose electrons. The position of a metal in the electrochemical series determines the method of extraction that should be used. For example, metals at the top of the series are usually extracted by electrolysis, which involves passing an electric current through a molten compound of the metal. This process is necessary because the metals at the top of the series are very reactive and are strongly bonded to other elements in their ores. On the other hand, metals at the bottom of the series are usually extracted by reduction with carbon or hydrogen. This is because these metals are less reactive and can be separated from their ores by reacting them with a reducing agent that can take away the oxygen and other impurities. Therefore, the position of the metal in the electrochemical series is a crucial factor in determining the method of extraction that should be used to extract it from its ores.
Frage 36 Bericht
To what temperature must a gas at 273k be heated in order to double both its volume and pressure?
Frage 37 Bericht
According to Charles' law, the volume of a gas becomes zero at
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Charles' law states that the volume of a gas is directly proportional to its temperature, provided that the pressure remains constant. This means that as the temperature of a gas increases, its volume also increases. However, it is important to note that this law only applies to ideal gases, which are theoretical gases that perfectly follow the laws of thermodynamics. According to Charles' law, the volume of a gas becomes zero at absolute zero, which is approximately -273°C. At this temperature, the gas particles would have no kinetic energy and would be in their lowest energy state. The volume of a real gas would not actually become zero at absolute zero because the gas particles would have some residual intermolecular interactions that would prevent them from completely collapsing to a single point.
Frage 38 Bericht
To what volume must 300cm3 of 0.60M sodium hydroxide solution be diluted to give a 0.40M solution?
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Frage 39 Bericht
Methanoic acid mixes with water in all proportions and has about the same boiling point as water. Which of the following methods would you adopt to obtain pure water from a mixture of Sand, water and methanoic acid?
