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Question 1 Report
A certain hydrocarbon on complete combustion at s.t.p produced 89.6dm3 of CO2 and 54g of water. The hydrocarbon should be
Answer Details
In the question above an Hydrocarbon combust to give CO2 and H20
Let Hydrocarbon be
CxHy + x+Y/4O2= xCO2 + Y/2H2O
Mass of C0=44g and H2O=18g
at STP vol= 22.4
Therefore, 1mole of CO2 contains 44g and 22.4dm³ at STP
1mole = 22.4dm³
xmole = 89.6dm³
Cross multiplying x=89.6/22.4 =4mole of CO2 produce
1mole of H2O = 18g
Xmole = 56g
Cross multiplying
X = 56/18 = 3mole of H20
Then....
CxHy + X + y/4O2 = 4CO2+ 3H2O
Balancing
C4H6 + 6O2 = 4CO2 + 3H2O
Question 2 Report
Methane is prepared in the laboratory by heating a mixture of sodium ethanoate with soda lime. The chemical constituent(s) of soda lime is/are
Answer Details
The chemical constituent of soda lime used to prepare methane in the laboratory is Ca(OH)2 (calcium hydroxide) and NaOH (sodium hydroxide). Soda lime is a mixture of these two compounds. When sodium ethanoate (NaC2H3O2) is heated with soda lime, it undergoes a reaction known as the Kolbe's reaction, which produces methane gas (CH4) as one of the products. The reaction can be represented as follows: 2NaC2H3O2 + 2Ca(OH)2 → 2CH4 + 2NaOH + 2CaCO3 In this reaction, the sodium ethanoate reacts with the calcium hydroxide to form calcium acetate (Ca(C2H3O2)2) and sodium hydroxide. The calcium acetate then decomposes to produce methane gas and calcium carbonate (CaCO3), which is a solid precipitate. Therefore, the chemical constituents of soda lime used to prepare methane in the laboratory are calcium hydroxide (Ca(OH)2) and sodium hydroxide (NaOH).
Question 3 Report
By what amount must the temperature of 200cm3 of Nitrogen at 27°C be increased to double the pressure if the final volume is 150cm3 (Assume ideality)
Answer Details
Using the ideal gas law and equation:
P1V1T1=P2V2T2
P1×200cm3300K=2P×150cm3T2
Cross multiply:
T2=300×150×2P200×P
=450K
or 177∘C
Don't forget to convert to ∘C
Question 4 Report
X is a substance which liberates CO2 on treatment with concentrated H2 SO4 . A warm solution of X can decolorize acidified KMnO4 . X is
Answer Details
It should be noted that for X to liberate CO2
, X must be a carbonate or an oxalate. Since X decolorizes KMnO4
, X must be an oxalate.
Therefore, X is H2
C2
O4
.
Question 5 Report
Burning magnesium ribbon in air removes which of the following
(i) oxygen (ii) nitrogen (iii) argon and (iv) carbon(iv)oxide?
Answer Details
Burning magnesium ribbon in air will remove oxygen (option i) from the air, but not nitrogen (option ii), argon (option iii), or carbon dioxide (option iv). When magnesium burns, it reacts with oxygen in the air to form magnesium oxide. The reaction can be represented by the following equation: 2Mg(s) + O2(g) → 2MgO(s) The magnesium in the ribbon combines with oxygen in the air to form solid magnesium oxide. This reaction is exothermic, which means that it releases heat and light energy. So, when magnesium ribbon is burned in air, it consumes the oxygen in the air to form magnesium oxide. However, nitrogen, argon, and carbon dioxide are not chemically reactive with magnesium, and therefore are not removed from the air by the burning of magnesium ribbon. In summary, the correct option is (i) only - burning magnesium ribbon in air removes oxygen only.
Question 6 Report
In the reaction:
M + N → P
ΔH = +Q kJWhich of the following would increase the concentration of the product?
Answer Details
Increasing the temperature would increase the concentration of the product, P. The reaction rate, or the speed at which the reaction occurs, is influenced by temperature. An increase in temperature raises the kinetic energy of the reacting molecules, making it easier for them to collide and react. This leads to a higher rate of reaction and a higher concentration of the product, P. Adding a suitable catalyst can also increase the reaction rate, but it does not directly affect the concentration of the product. Increasing the concentration of P does not affect the reaction itself, but is a result of the reaction having taken place. Decreasing the temperature would slow down the reaction rate and reduce the concentration of the product.
Question 7 Report
The molecular shape and bond angle of water are respectively
Answer Details
The shape of water molecule = Bent/ V- shaped
The bond angle of water = 104.5°/ 105°
Question 8 Report
Consider the reaction: A + 2B(g)⇌ 2C + D(g) (Δ H = +ve)
What will be the effect of decrease in temperature on the reaction?
Answer Details
The effect of a decrease in temperature on the reaction will be that the rate of the backward reaction will increase. In a chemical reaction, the rate of the forward and backward reactions are determined by the activation energy required for each step and the temperature of the system. When the temperature is decreased, the rate of the reaction decreases, and the rate of the backward reaction increases. This shift in the rate of the backward reaction means that there will be a shift in the position of the equilibrium of the reaction. As the rate of the backward reaction increases, the concentration of the reactants will increase and the concentration of the products will decrease, leading to a decrease in the overall yield of the products. In this reaction, as ΔH (the change in enthalpy) is positive, which means that the reaction is endothermic. Endothermic reactions absorb heat from the surroundings to proceed, so a decrease in temperature will lead to a decrease in the rate of the forward reaction and an increase in the rate of the backward reaction. This shift in the rate of the backward reaction will shift the position of the equilibrium of the reaction to the left, leading to an increase in the concentration of the reactants and a decrease in the concentration of the products.
Question 9 Report
Hydrogen diffused through a porous plug
Answer Details
Hydrogen gas (H2) diffuses faster than oxygen gas (O2) through a porous plug. This is because the rate of diffusion of a gas through a porous plug is inversely proportional to the square root of its molar mass. Since the molar mass of hydrogen (2 g/mol) is much smaller than that of oxygen (32 g/mol), the rate of diffusion of hydrogen through a porous plug is much faster than that of oxygen. To be more specific, the ratio of the diffusion rates of two gases through a porous plug is given by the equation: Rate of diffusion of gas A / Rate of diffusion of gas B = √(Molar mass of gas B / Molar mass of gas A) Using the molar masses of hydrogen and oxygen, we get: Rate of diffusion of hydrogen / Rate of diffusion of oxygen = √(32 g/mol / 2 g/mol) = √16 = 4 Therefore, hydrogen diffuses through a porous plug four times as fast as oxygen. Thus, the correct answer is: four times as fast as oxygen.
Question 10 Report
Which quantum divides shells into orbitals?
Answer Details
The quantum that divides shells into orbitals is the "Azimuthal" quantum number, also known as the "angular momentum" quantum number. The azimuthal quantum number determines the shape of an electron's orbital, which is a region in space where there is a high probability of finding an electron. It describes the angular momentum of an electron in an atom and the number of subshells within a given shell. Each subshell is associated with a specific shape, and can hold a certain number of electrons. The azimuthal quantum number is represented by the letter "l" and can have integer values ranging from 0 to (n-1), where "n" is the principal quantum number. Each value of "l" corresponds to a different subshell shape: - l = 0 corresponds to an "s" subshell, which is spherical in shape. - l = 1 corresponds to a "p" subshell, which has a dumbbell shape with two lobes. - l = 2 corresponds to a "d" subshell, which has a more complex shape with four lobes and a doughnut-like ring. - l = 3 corresponds to an "f" subshell, which has an even more complex shape with eight lobes. The number of orbitals within a subshell is equal to 2l+1. For example, a "p" subshell (l = 1) has three orbitals (2l+1 = 3), which are labeled as "px", "py", and "pz". In summary, the azimuthal quantum number determines the shape of the electron's orbital and the number of subshells within a given shell, and it is represented by the letter "l".
Question 11 Report
Which of the following gases contains the least number of atoms at s.t.p?
Answer Details
At standard temperature and pressure (s.t.p), all gases have the same number of atoms or molecules. What changes between them is the volume they occupy, and this is dependent on their molecular mass and the number of moles. Comparing the number of moles between the gases listed above, 7 moles of argon will contain the most number of atoms, followed by 4 moles of chlorine, then 3 moles of ozone, and finally 1 mole of butane would contain the least number of atoms. In summary, the number of atoms in a gas sample depends on the number of moles, but at s.t.p, the volume occupied by each gas depends on its molecular mass and the number of moles.
Question 12 Report
The IUPAC nomenclature of the compound
H3 C - CH(CH3 ) - CH(CH3 ) - CH2 - CH3
Question 13 Report
Consider the equation below:
Cr2 O2−7 + 6Fe2+ + 14H+ → 2Cr3+ + 6Fe3+ + 7H2 O.
The oxidation number of chromium changes from
Answer Details
Cr2
O2−7
+ 6Fe2+
+ 14H+
→
2Cr3+
+ 6Fe3+
+ 7H2
O
The oxidation of Cr in Cr2
O2−7
:
Let the oxidation of Cr = x;
2x + (-2 x 7) = -2 ⟹
2x - 14 = -2
2x = 12 ; x = +6
Hence, the change in oxidation of Cr = +6 to +3
Question 14 Report
Na2 CO3 + 2HCl → 2NaCl + H2 O + CO2
The indicator most suitable for this reaction should have a pH equal to
Answer Details
Methyl orange is the best indicator for the reaction with range 3.1 - 4.4.
Question 15 Report
What volume of 0.100M sodium trioxonitrate (V) solution contains 5g of solute.
[Na = 23, N = 14, O = 16]
Answer Details
To calculate the volume of a solution, we need to use the formula: moles of solute = concentration x volume First, let's find the number of moles of sodium trioxonitrate (V) in 5g of the solute. The molar mass of NaNO3 is: Na = 23 N = 14 3 x O = 3 x 16 = 48 Molar mass = 23 + 14 + 48 = 85 g/mol The number of moles of NaNO3 in 5g is: moles = mass / molar mass = 5 / 85 = 0.0588 moles Now, we can use the formula above to find the volume of the solution: moles of solute = concentration x volume volume = moles of solute / concentration volume = 0.0588 moles / 0.100 M volume = 0.588 litres Therefore, the correct answer is 0.588 litres of 0.100M sodium trioxonitrate (V) solution contains 5g of solute.
Question 16 Report
The emission of two successive beta particles from the nucleus 3215P will produce
Answer Details
Question 17 Report
If the cost of electricity required to discharge 10g of an ion X3+ is N20.00, how much would it cost to discharge 6g of ion Y2+ ?
[1 faraday = 96,500C, atomic masses are X = 27, Y = 24]
Answer Details
X3+
+ 3e−
→
X
3F = 27g
xF = 10g
x3=1027⟹x=109F
109
F ≡
N20.00
1F is equivalent to x
1109=x20
910=x20⟹x=N18.00
1F is equivalent to N18.00.
Y2+
+ 2e−
→
Y
2F = 24g
xF = 6g
x = 6×224=12F
1F = N18.00
12
F = 12×N18.00
= N9.00
Question 18 Report
Which of the following could not be alkane?
Answer Details
An alkane is a type of hydrocarbon with only single bonds between the carbon atoms. It follows the general formula CnH2n+2, where "n" is the number of carbon atoms in the molecule. To determine whether a molecule is an alkane or not, we can calculate its molecular formula and check if it fits the general formula of alkane. Out of the given options, the third one (C7H14) cannot be an alkane. To see why, let's use the general formula of alkane, which is CnH2n+2. For C7H14 to be an alkane, it should have 2n+2 = 2(7) + 2 = 16 hydrogen atoms. However, C7H14 has only 14 hydrogen atoms, which means it does not follow the general formula of alkane. Therefore, C7H14 cannot be an alkane. The other options are as follows: - C4H10: This is butane, which is an alkane with four carbon atoms. - C5H12: This is pentane, which is an alkane with five carbon atoms. - C8H18: This is octane, which is an alkane with eight carbon atoms. In summary, the molecule C7H14 cannot be an alkane because it does not follow the general formula of alkane, while the other options are all examples of alkanes.
Question 19 Report
How many electrons will be found in the nucleus of an atom with mass number 23 and 17 neutrons?
Answer Details
Electrons are not found in the nucleus of an atom. The nucleus of an atom only contains protons and neutrons, while electrons are located outside the nucleus in the electron cloud. The mass number of an atom is equal to the sum of the number of protons and the number of neutrons in the nucleus. Therefore, if an atom has a mass number of 23 and 17 neutrons, then the number of protons in the nucleus can be calculated as: Protons = Mass number - Neutrons Protons = 23 - 17 Protons = 6 This means that the nucleus of the atom contains 6 protons. The number of electrons in a neutral atom is equal to the number of protons, so the atom also contains 6 electrons in the electron cloud surrounding the nucleus. In summary, the answer is that there are 6 protons and 6 electrons in the atom.
Question 20 Report
Which of the following pairs cannot be represented with a chemical formula?
Answer Details
The pair that cannot be represented with a chemical formula is air and bronze. Air is a mixture of several gases, primarily nitrogen (N₂) and oxygen (O₂), with small amounts of other gases such as argon (Ar), carbon dioxide (CO₂), and neon (Ne). Since air is a mixture and not a pure substance, it cannot be represented by a chemical formula. Bronze, on the other hand, is an alloy composed mainly of copper (Cu) and tin (Sn) with small amounts of other metals. The composition of bronze can vary depending on the specific alloy, but it can be represented by a chemical formula such as CuSn. Sodium chloride (NaCl) is a compound composed of sodium (Na) and chlorine (Cl) in a fixed ratio of 1:1, and it can be represented by a chemical formula. Similarly, copper (Cu) and sodium chloride (NaCl) can each be represented by a chemical formula. Cu is an element, so its chemical formula is simply its symbol, while NaCl is a compound with a fixed ratio of sodium and chlorine atoms. Caustic soda (sodium hydroxide, NaOH) and washing soda (sodium carbonate, Na₂CO₃) are both compounds that can be represented by chemical formulas. NaOH consists of one sodium atom, one oxygen atom, and one hydrogen atom, while Na₂CO₃ consists of two sodium atoms, one carbon atom, and three oxygen atoms.
Question 21 Report
For the general equation of the nature
XP + yQ ⇌ mR + nS, the expression for the equilibrium constant is
Answer Details
The expression for the equilibrium constant for the general equation XP + yQ ⇌ mR + nS is: Kc = [R]m[S]n / [P]x[Q]y where Kc is the equilibrium constant, [R] and [S] are the concentrations of the products, and [P] and [Q] are the concentrations of the reactants, all raised to the stoichiometric coefficients (m, n, x, y) in the balanced equation. This equation is known as the equilibrium constant expression and it represents the ratio of the concentrations of the products and reactants at equilibrium for a particular chemical reaction. The equilibrium constant is a measure of how far a reaction proceeds towards completion, with a larger value indicating a greater extent of reaction. The equilibrium constant expression is derived from the law of mass action, which states that the rate of a chemical reaction is proportional to the product of the concentrations of the reactants raised to their stoichiometric coefficients. At equilibrium, the rates of the forward and reverse reactions are equal, and the equilibrium constant expression represents the ratio of the rate constants for these two reactions. Therefore, the correct expression for the equilibrium constant for the general equation XP + yQ ⇌ mR + nS is Kc = [R]m[S]n / [P]x[Q]y.
Question 22 Report
The part of the total energy of a system that accounts for the useful work done in a system is known as
Answer Details
The part of the total energy of a system that accounts for the useful work done in a system is known as "Gibbs free energy". Gibbs free energy is a thermodynamic property that represents the amount of energy that can be converted into useful work in a system. It takes into account both the energy of the system and the entropy, or disorder, of the system. In other words, Gibbs free energy is a measure of the energy available to do work, taking into account the energy that is unavailable due to entropy. In simple terms, if a system has a high Gibbs free energy, it has a lot of energy available to do work, and if a system has a low Gibbs free energy, it has little energy available to do work.
Question 23 Report
When ammonia and hydrogen ion bond together to form ammonium ion, the bond formed is called
Answer Details
When ammonia and hydrogen ion go into bonding, they form ammonium ion by combining with a dative/coordinate covalent bond.
Question 24 Report
The oxidation state(s) of nitrogen in ammonium nitrite is/are
Answer Details
Ammonium nitrite = NH4
NO2
NH+4
: Let the oxidation number of Nitrogen = x
x + 4 = 1 ⟹
x = 1 - 4
x = -3
NO−2
: x - 4 = -1
x = -1 + 4 ⟹
x = +3.
The oxidation numbers for Nitrogen in Ammonium Nitrite = -3, +3.
Question 26 Report
The electronic configuration of element Z is 1s2 2s2 2p6 3s2 3p1 . What is the formula of the compound formed between Z and tetraoxosulphate (VI) ion.
Answer Details
Z = 1s2
2s2
2p6
3s2
3p1
?
We have Z3+
and SO2?4
The reaction : Z3+
+ SO2?4
?
Z2
(SO4
)3
.
Question 27 Report
An element Z contains 80% of 168 Z and 20% of 188 Z. Its relative atomic mass is
Answer Details
R.A.M of Z = 16(80100)+18(20100)
= 12.8+3.6
= 16.4
Question 28 Report
Which of the following sets of operation will completely separate a mixture of sodium chloride, sand and iodine?
Answer Details
The set of operations that will completely separate a mixture of sodium chloride, sand, and iodine is: - filtration, to separate the sand and iodine from the sodium chloride - evaporation to dryness, to concentrate the sodium chloride solution and remove any remaining water - sublimation, to separate the iodine as a solid from the remaining sodium chloride By using these operations, you can separate each component of the mixture into separate, pure forms. The order of the operations is important because each step must be done in a way that effectively separates the components and does not interfere with subsequent steps.
Question 29 Report
At 27°C, 58.5g of sodium chloride is present in 250cm3 of a solution. The solubility of sodium chloride at this temperature is?
(molar mass of sodium chloride = 111.0gmol−1 )
Answer Details
Given the Mass of the salt = 58.5g
Volume = 250 cm3
= 0.25 dm3
Mass concentration = MassVolume
= 58.50.25
= 234 gdm−3
Solubility (in moldm−3
= 234111
= 2.11 moldm−3
≊
2.0 moldm−3
Question 30 Report
Which of the following conditions will most enhance the spontaneity of a reaction?
Answer Details
The condition that will most enhance the spontaneity of a reaction is when ΔH is negative (i.e., the reaction releases heat) and ΔS is positive (i.e., the reaction increases the disorder or randomness of the system). This is because a negative ΔH indicates that the reaction releases energy, which is favorable for a spontaneous reaction, while a positive ΔS indicates that the system becomes more disordered, which is also favorable for spontaneous reactions. Among the given options, the first condition of a negative and greater ΔH than ΔS is the best option for enhancing the spontaneity of a reaction. The other options have either a positive ΔH or a zero ΔS, which is not favorable for spontaneous reactions.
Question 31 Report
Which of the following metals is the most essential in the regulation of blood volume, blood pressure and osmotic equilibrium?
Answer Details
The metal that is most essential in the regulation of blood volume, blood pressure, and osmotic equilibrium is sodium. Sodium is a key electrolyte that helps maintain the balance of fluids in the body, including blood volume and blood pressure. Sodium ions are positively charged and are attracted to negatively charged ions, such as chloride (Cl-) and bicarbonate (HCO3-), which together help regulate the pH of the blood. Sodium is also essential for maintaining osmotic equilibrium, which refers to the balance of solutes between cells and the extracellular fluid. Osmotic equilibrium is critical for proper cellular function and is regulated by the movement of water and electrolytes, including sodium, in and out of cells. While the other metals listed (zinc, manganese, and iron) are important for various functions in the body, such as enzyme activity and oxygen transport, they are not directly involved in regulating blood volume, blood pressure, and osmotic equilibrium in the same way that sodium is. Therefore, the answer is not options 1, 2, or 4, and the correct answer is: sodium.
Question 33 Report
What technique is suitable for separating a binary solution of potassium chloride and potassium trioxochlorate (V)?
Answer Details
Fractional crystallization is the most suitable technique for separating a binary solution of potassium chloride and potassium trioxochlorate (V). This is because fractional crystallization is a process that separates a mixture of substances based on their solubility in a solvent at a particular temperature. In this case, potassium chloride and potassium trioxochlorate (V) have different solubilities in a solvent such as water at different temperatures. By carefully controlling the temperature, the solubility of each compound can be selectively increased or decreased, allowing them to be separated by crystallization. The less soluble compound will form crystals first and can be separated from the more soluble compound, which remains in the solution. Therefore, fractional crystallization can be used to separate potassium chloride and potassium trioxochlorate (V) in a binary solution.
Question 34 Report
A radioactive nucleus has a half-life of 20 years, starting with 100,000 particles, how many particles will be left exactly at the end of 40 years
Answer Details
The half-life of a radioactive nucleus is the time it takes for half of its particles to decay. This means that after 20 years, 100,000 particles will become 50,000 particles. After 40 years, we can find the number of particles remaining by counting the number of half-lives that have passed. Since 40 years is double the half-life of 20 years, this means that two half-lives have passed, so the number of particles will be halved twice. Starting with 100,000 particles: - After 1 half-life (20 years), there will be 50,000 particles remaining. - After 2 half-lives (40 years), there will be 25,000 particles remaining. So, exactly at the end of 40 years, there will be 25,000 particles remaining.
Question 35 Report
The two ions responsible for hardness in water are
Answer Details
The ions responsible for hardness in water are Ca2+ and/or Mg2+. Hardness in water refers to the presence of calcium and magnesium ions, which are commonly found in natural water sources such as rivers, lakes, and groundwater. These ions can react with soap to form insoluble compounds, reducing the effectiveness of soap and causing scaling in pipes and appliances. The hardness of water is often measured in terms of the concentration of calcium and magnesium ions, expressed as calcium carbonate equivalents (CaCO3).
Question 36 Report
A cell shorthand notation can be written as A / A+ // B2+ /B. The double slash in the notation represents the
Answer Details
The double slash in the cell shorthand notation represents the salt bridge. A salt bridge is a component of an electrochemical cell that connects the two half-cells and allows the flow of ions between them. It consists of an inert electrolyte solution (usually a salt) that is placed between the two half-cells. The purpose of the salt bridge is to maintain electrical neutrality in each half-cell by allowing the flow of ions to balance the charge buildup in the half-cells. In the cell shorthand notation, the double slash "//" represents the salt bridge that connects the two half-cells of the electrochemical cell. The first half-cell is represented on the left-hand side of the slash and the second half-cell is represented on the right-hand side of the slash. The anode (where oxidation occurs) is represented on the left side, and the cathode (where reduction occurs) is represented on the right side. Therefore, the correct answer is option number 3: salt bridge.
Question 37 Report
Which of the following statements does not show Rutherford's account of Nuclear Theory? An atom contains a region
Answer Details
Rutherford's account of Nuclear theory does not include the fact that atoms contain a massive region and cause deflection of from projectiles.
Question 38 Report
The hybridization in the compound CH3−CH2−C≡H is
Answer Details
The hybridization in a and b is sp3 hybridization while in c and d is sp hybridization.
Question 39 Report
The combustion of carbon(ii)oxide in oxygen can be represented by equation.
2CO + O2 ? 2CO2
Calculate the volume of the resulting mixture at the end of the reaction if 50cm3 of carbon(ii)oxide was exploded in 100cm3 of oxygen
Answer Details
Question 40 Report
Which of the following alkaline metals react more quickly spontaneously with water?
Answer Details
The alkaline earth metals (Be, Mg, Ca, Sr, Ba, and Ra) are the second most reactive metals in the periodic table, and, like the Group 1 metals, have increasing reactivity in the higher periods. Beryllium (Be) is the only alkaline earth metal that does not react with water or steam, even if metal is heated to red heat. Additionally, beryllium has a resistant outer oxide layer that lowers its reactivity at lower temperatures.
Magnesium shows insignificant reaction with water, but burns vigorously with steam or water vapor to produce white magnesium oxide and hydrogen gas:
A metal reacting with cold water will produce metal hydroxide. However, if a metal reacts with steam, like magnesium, metal oxide is produced as a result of metal hydroxides splitting upon heating.
The hydroxides of calcium, strontium and barium are only slightly water-soluble but produce sufficient hydroxide ions to make the environment basic, giving a general equation of:
Order of reactivity | Metal | Reactions with water or steam |
---|---|---|
most reactive | potassium (K) | very vigorous reaction with cold water |
↑ | sodium (Na) | vigorous reaction with cold water |
↓ | calcium (Ca) | less vigorous reaction with cold water |
least reactive | magnesium (Mg) | slow reaction with cold water, vigorous with steam |
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